How to Make Ceramic Glass Look New Again
Ceramic Tile
Background
Wall and floor tile used for interior and exterior decoration belongs to a form of ceramics known every bit whitewares. The production of tile dates dorsum to aboriginal times and peoples, including the Egyptians, the Babylonians, and the Assyrians. For instance, the Footstep Pyramid for the Pharoah Djoser, built in aboriginal Arab republic of egypt effectually 2600 B.C. , contained colorful glazed tile. Later, ceramic tile was manufactured in virtually every major European state and in the United States. By the commencement of the twentieth century, tile was manufactured on an industrial scale. The invention of the tunnel kiln around 1910 increased the automation of tile manufacture. Today, tile manufacture is highly automated.
The American National Standards Institute separates tiles into several classifications. Ceramic mosaic tile may be either porcelain or of natural clay composition of size less than 39 cm2 (half dozen in.ii). Decorative wall tile is glazed tile with a thin body used for interior decoration of residential walls. Paver tile is glazed or unglazed porcelain or natural clay tile of size 39 cm2 (half dozen in.ii) or more. Porcelain tile is ceramic mosaic tile or paver tile that is fabricated by a certain method called dry pressing. Quarry tile is glazed or unglazed tile of the same size every bit paver tile, but fabricated by a different forming method.
Europe, Latin America, and the Far East are the largest producers of tile, with Italian republic the leader at 16.6 1000000 ft.2/day as of 1989. Following Italy (at 24.half-dozen percentage of the world marketplace) are Spain (12.6 pct), Brazil and Germany (both at 11.2 percent), and the The states (4.five pct). The total marketplace for floor and wall tile in 1990 according to one gauge was $2.iv billion.
The United States has approximately 100 plants that manufacture ceramic tile, which shipped about 507 1000000 ft.two in 1990 according to the U.S. Department of Commerce. U.S. imports, by book, accounted for approximately 60 percent of consumption in 1990, valued at around $500 million. Italia accounts for almost half of all imports, with Mexico and Kingdom of spain following. U.Southward. exports accept seen some growth, from $12 million in 1988 to about $20 million in 1990.
Because the tile industry is a relatively mature market and dependent on the edifice industry, growth volition be slow. The United States Department of Commerce estimates a three to four per centum increase in tile consumption over the next 5 years. Another economic analysis predicts that 494 million ft.2 will be shipped in 1992, a growth of nigh four percent from the previous year. Some tile manufacturers are a fleck more optimistic; an American Ceramic Society survey showed an average growth of effectually 36 percent per manufacturer over the side by side five years.
Raw Materials
The raw materials used to form tile consist of clay minerals mined from the world'south crust, natural minerals such as feldspar that are used to lower the firing temperature, and chemic additives required for the shaping process. The minerals are often refined or beneficiated near the mine before shipment to the ceramic plant.
The raw materials must exist pulverized and classified according to particle size. Primary crushers are used to reduce big lumps of textile. Either a jaw crusher or gyratory crusher is used, which operate using a horizontal
squeezing motion between steel plates or rotating motion between steel cones, respectively.
Secondary crushing reduces smaller lumps to particles. Hammer or muller mills are often used. A muller mill uses steel wheels in a shallow rotating pan, while a hammer mill uses rapidly moving steel hammers to beat out the material. Roller or cone type crushers tin can also be used.
A 3rd particle size reduction step may be necessary. Tumbling types of mills are used in combination with grinding media. One of the most common types of such mills is the brawl mill, which consists of large rotating cylinders partially filled with spherical grinding media.
Screens are used to separate out particles in a specific size range. They operate in a sloped position and are vibrated mechanically or electromechanically to improve fabric menstruation. Screens are classified according to mesh number, which is the number of openings per lineal inch of screen surface. The higher the mesh number, the smaller the opening size.
A coat is a glass cloth designed to melt onto the surface of the tile during firing, and which and so adheres to the tile surface during cooling. Glazes are used to provide moisture resistance and ornamentation, every bit they can be colored or can produce special textures.
The Manufacturing
Process
Once the raw materials are processed, a number of steps take place to obtain the finished product. These steps include batching, mixing and grinding, spray-drying, forming, drying, glazing, and firing. Many of these steps are now accomplished using automatic equipment.
Batching
- i For many ceramic products, including tile, the body composition is determined by the amount and blazon of raw materials. The raw materials also determine the color of the tile trunk, which tin exist carmine or white in colour, depending on the corporeality of iron-containing raw materials used. Therefore, it is important to mix the right amounts together to achieve the desired properties. Batch calculations are thus required, which must accept into consideration both physical properties and chemical compositions of the raw materials. Once the advisable weight of each raw textile is determined, the raw materials must be mixed together.
Mixing and grinding
- ii One time the ingredients are weighed, they are added together into a shell mixer, ribbon mixer, or intensive mixer. A crush mixer consists of two cylinders joined into a V, which rotates to tumble and mix the fabric. A ribbon mixer uses helical vanes, and an intensive mixer uses rapidly revolving plows. This step further grinds the ingredients, resulting in a effectively particle size that improves the subsequent forming process (see step #four beneath).
Sometimes it is necessary to add water to improve the mixing of a multiple-ingredient batch as well as to achieve fine grinding. This process is called wet milling and is oft performed using a brawl mill. The resulting water-filled mixture is called a slurry or slip. The water is then removed from the slurry by filter pressing (which removes 40-50 percent of the moisture), followed past dry milling.
Spray drying
- three If wet milling is first used, the backlog water is usually removed via spray drying. This involves pumping the slurry to an atomizer consisting of a chop-chop rotating deejay or nozzle. Aerosol of the slip are dried every bit they are heated by a ascension hot air column, forming minor, free flowing granules that upshot in a powder suitable for forming.
Tile bodies can likewise be prepared past dry grinding followed by granulation. Granulation uses a auto in which the mixture of previously dry-ground material is mixed with h2o in order to form the particles into granules, which once more course a powder set up for forming.
Forming
- 4 Most tile is formed by dry pressing. In this method, the free flowing powder—containing organic binder or a depression percentage of wet—flows from a hopper into the forming dice. The material is compressed in a steel cavity by steel plungers and is then ejected by the bottom plunger. Automated presses are used with operating pressures equally high every bit two,500 tons.
Several other methods are also used where the tile body is in a wetter, more moldable grade. Extrusion plus punching is used to produce irregularly shaped tile and thinner tile faster and more than economically. This involves compacting a plastic mass in a loftier-pressure cylinder and forcing the textile to menstruum out of the cylinder into brusque slugs. These slugs are then punched into one or more tiles using hydraulic or pneumatic punching presses.
Ram pressing is often used for heavily profiled tiles. With this method, extruded slugs of the tile body are pressed between ii halves of a hard or porous mold mounted in a hydraulic press. The formed office is removed past showtime applying vacuum to the top half of the mold to free the part from the bottom half, followed by forcing air through the tiptop half to gratis the top part. Excess material must exist removed from the part and additional finishing may be needed.
Another process, chosen force per unit area glazing, has recently been developed. This process combines glazing and shaping simultaneously past pressing the coat (in spray-stale powder class) directly in the die filled with the tile body pulverisation. Advantages include the emptying of glazing lines, as well every bit the glazing waste material fabric (called sludge) that is produced with the conventional method.
Drying
- 5 Ceramic tile usually must be dried (at loftier relative humidity) after forming, specially if a moisture method is used. Drying, which can take several days, removes the water at a tedious enough rate to prevent shrinkage cracks. Continuous or tunnel driers are used that are heated using gas or oil, infrared lamps, or microwave energy. Infrared drying is ameliorate suited for thin tile, whereas microwave drying works amend for thicker tile. Another method, impulse drying, uses pulses of hot air flowing in the transverse management instead of continuously in the textile menstruum direction.
Glazing
- 6 To prepare the glaze, similar methods are used every bit for the tile trunk. After a batch formulation is calculated, the raw materials are weighed, mixed and dry or moisture milled. The milled glazes are and then applied using one of the many methods bachelor. In centrifugal glazing or discing, the glaze is fed through a rotating disc that flings or throws the coat onto the tile. In the bell/waterfall method, a stream of glaze falls onto the tile every bit it passes on a conveyor underneath. Sometimes, the glaze is merely sprayed on. For multiple glaze applications, screen printing on, under, or between tile that have been moisture glazed is used. In this process, glaze is forced through a screen by a rubber squeegee or other device.
Dry glazing is also being used. This involves the awarding of powders, crushed frits (glass materials), and granulated glazes onto a wet-glazed tile surface. After firing, the glaze particles melt into each other to produce a surface like granite.
Firing
- 7 After glazing, the tile must exist heated intensely to strengthen information technology and requite information technology the desired porosity. Two types of ovens, or
For tile that only requires a unmarried firing—usually tile that is prepared by moisture milling—roller kilns are more often than not used. These kilns move the wares on a roller conveyor and exercise not require kiln furnitures such equally batts or saggers. Firing times in roller kilns can exist as low as 60 minutes, with firing temperatures effectually 2,102 degrees Fahrenheit (1,150 degrees Celsius) or more.
- 8 After firing and testing, the tile is ready to be packaged and shipped.
Byproducts
A variety of pollutants are generated during the diverse manufacturing steps; these emissions must exist controlled to meet air control standards. Amongst the pollutants produced in tile manufacture are fluorine and pb compounds, which are produced during firing and glazing. Lead compounds have been significantly reduced with the recent development of no-lead or low-lead glazes. Fluorine emissions tin be controlled with scrubbers, devices that basically spray the gases with water to remove harmful pollutants. They can besides exist controlled with dry processes, such as fabric filters coated with lime. This lime can then be recycled as a raw material for future tile.
The tile manufacture is besides developing processes to recycle wastewater and sludge produced during milling, glazing, and spray-drying. Already some plants recycle the backlog powder generated during dry-pressing as well as the overspray produced during glazing. Waste product coat and rejected tile are also returned to the body preparation process for reuse.
Quality Command
Almost tile manufacturers now employ statistical process control (SPC) for each step of the manufacturing process. Many also work closely with their raw fabric suppliers to ensure that specifications are met before the material is used. Statistical process control consists of charts that are used to monitor various processing parameters, such as particle size, milling time, drying temperature and time, compaction pressure, dimensions afterwards pressing, density, firing temperature and time, and the like. These charts place issues with equipment, out of spec conditions, and help to meliorate yields before the terminal product is finished.
The final production must encounter certain specifications regarding physical and chemical properties. These properties are determined by standard tests established by the American Order of Testing and Materials (ASTM). Properties measured include mechanical strength, abrasion resistance, chemic resistance, water absorption, dimensional stability, frost resistance, and linear coefficient of thermal expansion. More recently, the slip resistance, which can exist determined by measuring the coefficient of friction, has become a concern. However, no standard has nonetheless been established considering other factors (such as proper floor blueprint and care) can make results meaningless.
The Future
In order to maintain market growth, tile manufacturers will concentrate on developing and promoting new tile products, including modular or cladding tile, larger-sized tile, slip- and abrasion-resistant tile, and tile with a polished, granite or marble cease. This is being accomplished through the development of different body formulations, new glazes, and coat applications, and past new and improved processing equipment and techniques. Automation volition continue to play an important role in an effort to increase production, lower costs, and better quality. In addition, changes in production engineering due to environmental and energy resource issues volition continue.
Where To Learn More
Books
Bough, W. and F. Handle, eds. Brick and Tile Making: Procedures and Operating Practices in the Heavy Clay Industries. Bauverlag GmbH, 1982.
Jones, J. T. and G. F. Berard. Ceramics: Industrial Processing and Testing. Iowa State University Printing, 1972.
Pellacani, K. and T. Manfredini. Engineered Materials Handbook. ASM International, 1991, pp. 925-929.
Periodicals
Burzacchini, B. "Technical Developments in Ceramic Tile Glazes and Related Applications," American Ceramic Gild Bulletin. March, 1991, pp. 394-403.
Fugmann, K. "Rapid Changes in Tile Technology," Tile & Brick International. March, 1991, pp. 165-166.
Gehringer, George. "Tile Glossary: A Guide to Techniques and Surface Designs," American Ceramic Lodge Bulletin. December, 1990, pp. 1950-1952.
Geiger, Greg. "Developments in the Tile Industry," American Ceramic Society Bulletin. December, 1991, pp. 1879-1885.
— L. South. Millberg
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